Physical and Mechanical Properties and Microstructure Characterization of Thermally Modified Flattened Bamboo (Phyllostachys edulis) Material

This study investigated the effects of thermal modification treatment on flattened bamboo lumber by using temperature (180 °C, 190 °C, 200 °C) and duration (2, 3, 4 h) as experimental variables. The physicochemical properties, crystallinity, bending deformation, chemical composition, and microstructural evolution of the material before and after treatment were systematically analyzed using universal mechanical testing, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and nanoindentation. This comprehensive approach aimed to achieve high-performance flattened bamboo lumber. The results revealed that thermal modification significantly reduced the flexural modulus of elasticity and hardness of the flattened bamboo lumber, which reached their minimum values of 4479 MPa and 786.71 N, under the treatment at 190 °C/3 h. Conversely, it enhanced the longitudinal compressive strength of flattened bamboo lumber, achieving a maximum value of 57.28 MPa at 180 °C/2 h. At the microscale, the nanomechanical strength decreased under 190–200 °C treatments, accompanied by a tighter cell arrangement and evident shrinkage and deformation of the parenchyma cells. Dimensional stability tests combined with FTIR and crystallinity analyses demonstrated a reduction in the number of hydrophilic groups and improved dimensional stability after thermal modification. Notably, the material treated at 200 °C for 4 h retained its dimensional stability and exhibited no deformation.