Study on the Effect and Mechanism of Plasma-Activated Water to Improve the Wettability of Coal Dust

Coal dust seriously affects the underground working environment. The current water-spray dust reduction technology uses a large amount of water and has a poor effect on coal dust with poor wettability. This study proposed a clean and sustainable technology using plasma-activated water (PAW) to alter the wettability of coal dust and improve its dust control effect. The PAW was prepared and its physical and mathematical properties were tested by a device designed in-house. The influence of PAW on the wettability of coal dust was determined by the coal dust contact angle experiments. The effect of PAW on the surface morphology of coal dust was analyzed by a scanning electron microscope. The effect of PAW on the pore structure of coal dust was analyzed through the specific surface area and pore size experiments. The results showed that PAW contained a large number of active substances such as H2O2, NO3−, and NO2−, showing strong and stable oxidation. PAW could significantly reduce the instantaneous contact angle of coal dust, and the higher the degree of coal dust metamorphism, the more significant the reduction effect. The surface morphology, pore volume, specific surface area, and fractal dimension of the coal dust were significantly changed after PAW treatment. PAW could transform the non-uniform three-dimensional spatial distribution of the coal dust surface into an approximate two-dimensional planar distribution, thus enhancing the wettability of the coal dust. With the increase in PAW ionization intensity, the contact angle of long-flame coal was negatively correlated with the mesoporous pore volume. The contact angle of gas coal was negatively correlated with the micropore volume and micropore specific surface area, and was positively correlated with the mesopore volume. The contact angle of meager lean coal was positively correlated with the macropore specific surface area. The surface morphology, pore volume, specific surface area, and fractal dimension changes in coal dust treated with PAW can reveal the wettability enhancement mechanism to some extent. The results of the study can provide pre-theoretical guidance for the field application of PAW coal mine dust reduction technology.