Coefficients of Thermal Expansion in Aligned Carbon Staple Fiber-Reinforced Polymers: Experimental Characterization with Numerical Investigation

Carbon staple fiber composites are materials reinforced with discrete-length carbon fibers processed using traditional textile technologies, offering moderate mechanical properties and flexibility in manufacturing. These composites can be produced from recycled carbon staple fibers, aligned into yarn and tape-like structures, providing a more sustainable alternative while balancing performance, cost-effectiveness, and environmental impact. Aligning staple fibers into tape-like structures enables similar applications to those of continuous-fiber-based products, while allowing control over fiber orientation distribution, fiber volume fraction, and length distribution, which are all critical factors influencing both mechanical and thermo-mechanical properties. This study focuses on the experimental characterization and numerical investigation of Coefficients of Thermal Expansion (CTEs) in aligned carbon staple fiber composites. The effects of fiber orientation and volume fraction on coefficients of thermal expansion under different fiber alignment parameters are analyzed, revealing distinct thermal expansion behavior compared to typical aligned unidirectional continuous carbon fiber composite laminates. Unlike continuous unidirectional laminates, which typically exhibit transversely isotropic behavior without tensile-shear coupling, staple fiber composites demonstrate different in-plane axial, transverse, and out-of-plane CTE characteristics. To explain these deviations, a modeling approach is introduced, incorporating detailed experimental information on fiber distributions and microstructural features rather than averaged fiber orientation values. This involves a multi-scale analysis based on a laminate analogy through which all composite thermo-elastic properties can be predicted, accounting for variations in fiber orientations, volume fractions, and tape thicknesses. It is shown that while the local variation of fiber volume fraction has a small effect on the homogenized value of the coefficients of thermal expansion, fiber misalignment, tape thickness, and asymmetry in fiber orientation distribution will significantly affect the measurements of CTEs. For the case of carbon staple fiber composites, the asymmetry in fiber orientation distribution significantly influences the measurements of axial CTE. Fiber orientation asymmetry causes tensile-shear coupling under mechanical and thermal loading, leading to an unbalanced laminate with in-plane shear-tensile deformation. This coupling disrupts uniform displacement, complicating strain measurements and the determination of composite properties.