2-(3-Hydroxyphenyl)-4,5-diphenyl-1<i>H</i>-imidazol-3-ium hemioxalate ethanol monosolvate

In the title imidazolium oxalate solvate, C 21 H 17 N 2 O + 0.5C 2 O 4 2 C 2 H 6 O, the cation and the ethanol solvent molecule are located on general positions, whereas the complete oxalate ion is generated by a crystallographic centre of symmetry.The study confirms two proton transfers from oxalic acid to the pyrimidine-type N atoms of two separate imidazole rings.The extended structure features strong N-H O and O-H O hydrogen-bond interactions.

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IUCrData
Published
2025-04-09
DOI
https://doi.org/10.1107/s2414314625003153
Primary Topic
Synthesis and Characterization of Heterocyclic Compounds
Type
article
Field-Weighted Citation Impact
0.00

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article

2-(3-Hydroxyphenyl)-4,5-diphenyl-1H-imidazol-3-ium hemioxalate ethanol monosolvate

M. Arockia doss, Peter Solo
IUCrData
Synthesis and Characterization of Heterocyclic Compounds
article

2-(3-Hydroxyphenyl)-4,5-diphenyl-1H-imidazol-3-ium hemioxalate ethanol monosolvate

M. Arockia doss, Peter Solo
article en

Abstract

In the title imidazolium oxalate solvate, C 21 H 17 N 2 O + 0.5C 2 O 4 2 C 2 H 6 O, the cation and the ethanol solvent molecule are located on general positions, whereas the complete oxalate ion is generated by a crystallographic centre of symmetry.The study confirms two proton transfers from oxalic acid to the pyrimidine-type N atoms of two separate imidazole rings.The extended structure features strong N-H O and O-H O hydrogen-bond interactions.

IUCrDataVol. 10(4)
Saint Joseph's College (US), Nagaland University (IN), St Xavier’s College (IN)
Tezpur University
Openalex Percentile: Top 94%
Synthesis and Characterization of Heterocyclic Compounds
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