Molten salts synthesized L‐Ta <sub>2</sub> O <sub>5</sub> :Er <sup>3+</sup> /Yb <sup>3+</sup> with superior pure green upconversion luminescence
Abstract L‐Ta 2 O 5 :Er 3+ /Yb 3+ upconversion phosphors were synthesized by employing the molten salts method with B 2 O 3 as solvent. The optimal doping concentrations of Er 3+ and Yb 3+ are 0.2 and 2.5 mol%, respectively. The green upconversion luminescence (UCL) integral intensity of the acid‐pickling sample reached 40% of β‐NaYF 4 :Er 3+ /Yb 3+ under 980 nm laser excitation. Er 3+ /Yb 3+ may take the sites of Ta 5+ and insert into the interlayers of L‐Ta 2 O 5 . Using the luminescence intensity ratio (LIR) technique, the relative temperature sensitivity was obtained to be 0.95 %K −1 at 303 K. L‐Ta 2 O 5 :Er 3+ /Yb 3+ with outstanding pure green UCL intensity and high‐temperature sensitivity can be applied to luminescence display and temperature sensing.
Authors
- Yuhan Fan (ORCID: https://orcid.org/0009-0000-8290-8896)
- Sai Xu (ORCID: https://orcid.org/0000-0001-7199-9673)
- Guojian Li
- Jinsu Zhang (ORCID: https://orcid.org/0009-0001-8514-2854)
- Yongze Cao (ORCID: https://orcid.org/0000-0001-7274-1551)
- Yichao Wang (ORCID: https://orcid.org/0000-0002-4429-5520)
- Baojiu Chen
- Meiling Li
- Shang Sun
Institutions
- Dalian Maritime University (CN)
- Northeastern University (CN)
Publication Details
- Journal
- Journal of the American Ceramic Society
- Published
- 2025-04-16
- DOI
- https://doi.org/10.1111/jace.20583
- Citations
- 3
- Primary Topic
- Luminescence Properties of Advanced Materials
- Type
- article
- Field-Weighted Citation Impact
- 1.55
Funders
- National Natural Science Foundation of China
- Fundamental Research Funds for the Central Universities