Multicomponent Synthesis of <i>S</i> ‑Vinyl Dithiocarbamates Using Vinyl Sulfonium Salts with CS <sub>2</sub> and Amines

Abstract A method for synthesizing dithiocarbamates via the ring‐opening of vinyl sulfonium salts, employing CS 2 and amines has been presented. The transformation can be performed rapidly at room temperature in ambient air without any additives. Additionally, the protocol features an extensive substrate range and simple reactive operations and affords the dithiocarbamates in a remarkably short time and elevated yields.

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Journal
ChemistrySelect
Published
2025-04-01
DOI
https://doi.org/10.1002/slct.202501354
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
0.00

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article

Multicomponent Synthesis of S ‑Vinyl Dithiocarbamates Using Vinyl Sulfonium Salts with CS 2 and Amines

Jingfeng Lan, Rulong Yan, Yapeng Zhang, Chengcheng Zhang et al.
ChemistrySelect
Sulfur-Based Synthesis Techniques
article

Multicomponent Synthesis of S ‑Vinyl Dithiocarbamates Using Vinyl Sulfonium Salts with CS 2 and Amines

Jingfeng Lan, Rulong Yan, Yapeng Zhang, Chengcheng Zhang, Peihua Liu, Bo Zhao, Jiaze Qin
article en

Abstract

Abstract A method for synthesizing dithiocarbamates via the ring‐opening of vinyl sulfonium salts, employing CS 2 and amines has been presented. The transformation can be performed rapidly at room temperature in ambient air without any additives. Additionally, the protocol features an extensive substrate range and simple reactive operations and affords the dithiocarbamates in a remarkably short time and elevated yields.

ChemistrySelectVol. 10(15)
Oil and Gas Center (CN), Lanzhou University (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 94%
Sulfur-Based Synthesis Techniques
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