Lithium from magma to mine in an early Yellowstone hotspot caldera

Abstract Renewable energy technologies rely on the extraction of metals not historically in high demand, such as lithium (Li), for which ore deposit models are incompletely understood. One of the world’s largest Li deposits is hosted in lake sediments of the 16.4 Ma McDermitt caldera, which formed during the early stages of Yellowstone hotspot volcanism in the western United States. Eruptive and posteruptive mobility of Li are major challenges in elucidating deposit formation. Melt inclusions preserved in quartz crystals provide a means to assess pre-eruptive magmatic Li contents. Concentrations of Li determined by ion microprobe for melt inclusions in a McDermitt rhyolite lava are 400–1350 ppm, compared to 20–70 ppm Li in matrix rhyolite glasses. Synthesis with melt inclusion data for eight additional calderas demonstrates a recurrence of Li-rich rhyolitic magmas (200–2000 ppm Li) in the western part of the Yellowstone hotspot track. However, unlike the multicyclic caldera complexes with overlapping fault networks that may have compromised Li retention, the McDermitt caldera remained a closed hydrologic system throughout its evolution. Modeling indicates 100 km3 of resurgent magma could yield 25–150 Mt Li in a magmatic fluid and supports accumulation of Li-rich magmatic fluid in a closed intracaldera lake, followed by evaporative concentration and sequestration of Li within clay minerals to generate the McDermitt deposit.