Cycloaddition reactivity of Yb@<i>D</i><sub>3h</sub>-C<sub>74</sub>: the carbon cage size matters
The cycloaddition between Yb@ D 3h -C 74 validates that the reduced carbon cage size of the Yb-based di-metallofullerenes, from C 84 to C 80 and then to C 74 , enables increased reactivity due to the elevated HOMO energy level and the narrowed bandgap.
Authors
- Xinde Li (ORCID: https://orcid.org/0000-0002-1529-4537)
- Shangfeng Yang (ORCID: https://orcid.org/0000-0002-6931-9613)
- Muqing Chen (ORCID: https://orcid.org/0000-0002-7111-1782)
- Jinrong Peng (ORCID: https://orcid.org/0000-0002-0793-4848)
- Jinpeng Xin (ORCID: https://orcid.org/0000-0001-8395-8983)
- Zhiyu Cheng (ORCID: https://orcid.org/0009-0005-3961-184X)
- Wang Xiang
- Yongfu Qiu
Institutions
- Hebei University of Technology (CN)
- Dongguan University of Technology (CN)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00649j
- Primary Topic
- Advanced Chemical Physics Studies
- Type
- article
- Field-Weighted Citation Impact
- 0.00