Silagermylenation of CO bonds and radical fragmentation of CO <sub>2</sub> -expanded bis(germylene) by a cyclic (alkyl)(amino)carbene

CO 2 and EtNCO are inserted into the Ge–Si bonds of an NHC-bis(germylene) with nucleophilic Ge( ii ) lone-pairs and an electrophilic para -silylenearylene backbone. CAAC-induced fragmentation yields a germylene with a tethered CAAC-radical.

Authors

Anna‐Lena Thömmes
Bernd Morgenstern (ORCID: https://orcid.org/0000-0002-8360-4218)
Christopher W. M. Kay (ORCID: https://orcid.org/0000-0002-5200-6004)
Dominik Munz (ORCID: https://orcid.org/0000-0003-3412-651X)
Michael Zimmer
David Scheschkewitz (ORCID: https://orcid.org/0000-0001-5600-8034)
Robin Völker

Institutions

London Centre for Nanotechnology (GB)
University College London (GB)
Saarland University (DE)

Publication Details

Journal: Inorganic Chemistry Frontiers
Published: 2025-01-01
DOI: https://doi.org/10.1039/d5qi00678c
Citations: 2
Primary Topic: Synthesis and characterization of novel inorganic/organometallic compounds
Type: article
Field-Weighted Citation Impact: 1.07

Funders

Deutsche Forschungsgemeinschaft
Universität des Saarlandes

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article

Silagermylenation of CO bonds and radical fragmentation of CO ₂ -expanded bis(germylene) by a cyclic (alkyl)(amino)carbene

Anna‐Lena Thömmes, Bernd Morgenstern, Christopher W. M. Kay, Dominik Munz et al.

Jan 1, 2025

2 citations

Inorganic Chemistry Frontiers

Synthesis and characterization of novel inorganic/organometallic compounds

1.07

article

Silagermylenation of CO bonds and radical fragmentation of CO ₂ -expanded bis(germylene) by a cyclic (alkyl)(amino)carbene

Anna‐Lena Thömmes, Bernd Morgenstern, Christopher W. M. Kay, Dominik Munz, Michael Zimmer, David Scheschkewitz, Robin Völker

January 1, 2025article en

2 citations

Abstract

CO 2 and EtNCO are inserted into the Ge–Si bonds of an NHC-bis(germylene) with nucleophilic Ge( ii ) lone-pairs and an electrophilic para -silylenearylene backbone. CAAC-induced fragmentation yields a germylene with a tethered CAAC-radical.

Inorganic Chemistry FrontiersVol. 12(16)

London Centre for Nanotechnology (GB), University College London (GB), Saarland University (DE)

Deutsche Forschungsgemeinschaft, Universität des Saarlandes

Openalex Percentile: Top 24%

Synthesis and characterization of novel inorganic/organometallic compounds

1.07

DOI Open Access PDF OpenAlex

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Silagermylenation of CO bonds and radical fragmentation of CO <sub>2</sub> -expanded bis(germylene) by a cyclic (alkyl)(amino)carbene — Anna‐Lena Thömmes, Bernd Morgenstern, et al. · Inorganic Chemistry Frontiers (2025) | TGRS Research Map | TGRS