Attractive and repulsive terms in multi-filament dispersion interactions

Filamentary objects such as nano-wires, nanotubes and DNA are of current interest in physics, nanoscience, chemistry, biology and medicine. They can interact <i>via</i> strong, exceptionally long-ranged many-object van der Waals (vdW, dispersion) forces, causing them to cluster into multi-object bundles. We analyse their vdW interactions perturbatively, predicting <i>N</i>-object vdW energy contributions that alternate in sign with increasing <i>N</i>. Our findings are confirmed here <i>via</i> the first detailed analysis of a 4-cylinder vdW model. We also provide novel insights permitting these tendencies to be understood simply in terms of electronic screening and anti-screening. Our results suggest that a non-perturbative calculation will be required for reliable prediction of dispersion interactions in these ubiquitous systems.

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Publication Details

Journal
Physical Chemistry Chemical Physics
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cp01117e
Primary Topic
Origins and Evolution of Life
Type
article
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article

Attractive and repulsive terms in multi-filament dispersion interactions

M. Boström, Subhojit Pal, John F. Dobson
Physical Chemistry Chemical Physics
Origins and Evolution of Life
article

Attractive and repulsive terms in multi-filament dispersion interactions

M. Boström, Subhojit Pal, John F. Dobson
article en

Abstract

Filamentary objects such as nano-wires, nanotubes and DNA are of current interest in physics, nanoscience, chemistry, biology and medicine. They can interact <i>via</i> strong, exceptionally long-ranged many-object van der Waals (vdW, dispersion) forces, causing them to cluster into multi-object bundles. We analyse their vdW interactions perturbatively, predicting <i>N</i>-object vdW energy contributions that alternate in sign with increasing <i>N</i>. Our findings are confirmed here <i>via</i> the first detailed analysis of a 4-cylinder vdW model. We also provide novel insights permitting these tendencies to be understood simply in terms of electronic screening and anti-screening. Our results suggest that a non-perturbative calculation will be required for reliable prediction of dispersion interactions in these ubiquitous systems.

Physical Chemistry Chemical PhysicsVol. 27(19)
Griffith University (AU), Institute of Electronic Materials Technology (PL), Ensemble Therapeutics (United States) (US), University of Warsaw (PL), University of Palermo (IT)
Openalex Percentile: Top 94%
Origins and Evolution of Life
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