Attractive and repulsive terms in multi-filament dispersion interactions
Filamentary objects such as nano-wires, nanotubes and DNA are of current interest in physics, nanoscience, chemistry, biology and medicine. They can interact <i>via</i> strong, exceptionally long-ranged many-object van der Waals (vdW, dispersion) forces, causing them to cluster into multi-object bundles. We analyse their vdW interactions perturbatively, predicting <i>N</i>-object vdW energy contributions that alternate in sign with increasing <i>N</i>. Our findings are confirmed here <i>via</i> the first detailed analysis of a 4-cylinder vdW model. We also provide novel insights permitting these tendencies to be understood simply in terms of electronic screening and anti-screening. Our results suggest that a non-perturbative calculation will be required for reliable prediction of dispersion interactions in these ubiquitous systems.
Authors
- M. Boström (ORCID: https://orcid.org/0000-0001-5111-4049)
- Subhojit Pal (ORCID: https://orcid.org/0009-0003-6356-3409)
- John F. Dobson (ORCID: https://orcid.org/0000-0002-7582-1378)
Institutions
- Griffith University (AU)
- Institute of Electronic Materials Technology (PL)
- Ensemble Therapeutics (United States) (US)
- University of Warsaw (PL)
- University of Palermo (IT)
Publication Details
- Journal
- Physical Chemistry Chemical Physics
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cp01117e
- Primary Topic
- Origins and Evolution of Life
- Type
- article
- Field-Weighted Citation Impact
- 0.00