Bio-derived chitosan additive enables anion anchoring and Zn(002) deposition for high-performance Zn anodes

Bio-derived quaternary-ammonium-functionalized chitosan (HACC) was investigated as an electrolyte additive for Zn anode stabilization, for the first time to the best of our knowledge. Due to its special structure, including abundant hydrophilic functional groups and positive charge, HACC can inhibit the hydrogen evolution reaction, promote Zn<sup>2+</sup> transport, and induce the deposition of Zn(002). Consequently, the electrolyte with HACC exhibits improved electrochemical performance.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc01325a
Citations
2
Primary Topic
Conducting polymers and applications
Type
article
Field-Weighted Citation Impact
1.21
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article

Bio-derived chitosan additive enables anion anchoring and Zn(002) deposition for high-performance Zn anodes

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2 citations
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article

Bio-derived chitosan additive enables anion anchoring and Zn(002) deposition for high-performance Zn anodes

Najun Liu, Xiaolei Jiang, Zhongchao Bai, Linna Guo, Nana Wang, Huili Peng, Mingbo Shao, Guanglu Jiang
article en
2 citations

Abstract

Bio-derived quaternary-ammonium-functionalized chitosan (HACC) was investigated as an electrolyte additive for Zn anode stabilization, for the first time to the best of our knowledge. Due to its special structure, including abundant hydrophilic functional groups and positive charge, HACC can inhibit the hydrogen evolution reaction, promote Zn<sup>2+</sup> transport, and induce the deposition of Zn(002). Consequently, the electrolyte with HACC exhibits improved electrochemical performance.

Chemical CommunicationsVol. 61(42)
University of Technology Sydney (AU), University of Shanghai for Science and Technology (CN), Linyi University (CN)
Clean water and sanitation
Openalex Percentile: Top 24%
Conducting polymers and applications
1.21
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