Electrocatalytic activity towards ORR correlated with synthesis methods and nitrogen functionality of polyaniline derived-nitrogen doped carbon materials

The present study investigates the electrocatalytic activity towards the oxygen reduction reaction (ORR) in alkaline solution of polyaniline derivednitrogen doped carbon materials (NDCMs) synthesized using three different methodsPANI1-900, PANI2-900 and PANI3-900. The electrocatalytic activity of carbonized PANIs towards ORR was correlated with the synthesis method used for polyaniline samples and the XPS and Raman data. The results show that the synthesis method used to produce PANI1 samples that have an increased content of protonated nitrogen (N+) species and a higher doping level is more suitable for the development of NDCMs materials with improved ORR activity.

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Publication Details

Journal
Romanian Reports in Physics
Published
2025-03-21
DOI
https://doi.org/10.59277/romrepphys.2025.77.501
Primary Topic
Conducting polymers and applications
Type
article
Field-Weighted Citation Impact
0.00

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article

Electrocatalytic activity towards ORR correlated with synthesis methods and nitrogen functionality of polyaniline derived-nitrogen doped carbon materials

Anca Dumitru
Romanian Reports in Physics
Conducting polymers and applications
article

Electrocatalytic activity towards ORR correlated with synthesis methods and nitrogen functionality of polyaniline derived-nitrogen doped carbon materials

Anca Dumitru
article en

Abstract

The present study investigates the electrocatalytic activity towards the oxygen reduction reaction (ORR) in alkaline solution of polyaniline derivednitrogen doped carbon materials (NDCMs) synthesized using three different methodsPANI1-900, PANI2-900 and PANI3-900. The electrocatalytic activity of carbonized PANIs towards ORR was correlated with the synthesis method used for polyaniline samples and the XPS and Raman data. The results show that the synthesis method used to produce PANI1 samples that have an increased content of protonated nitrogen (N+) species and a higher doping level is more suitable for the development of NDCMs materials with improved ORR activity.

Romanian Reports in PhysicsVol. 76(2)
University of Bucharest (RO)
National Authority for Scientific Research and Innovation, Autoritatea Natională pentru Cercetare Stiintifică, Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii, Colegiul Consultativ pentru Cercetare-Dezvoltare şi Inovare
Openalex Percentile: Top 94%
Conducting polymers and applications
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Electrocatalytic activity towards ORR correlated with synthesis methods and nitrogen functionality of polyaniline derived-nitrogen doped carbon materials — Anca Dumitru · Romanian Reports in Physics (2025) | TGRS Research Map | TGRS