A photocatalytic hydrogen atom transfer and aryl migration strategy for the arylalkylation of activated alkenes with 1-(<i>o</i>-iodoaryl)-alkan-1-ones

A visible-light catalyzed strategy for remote C(sp3)–H alkylation of 1-( o -iodoaryl)alkan-1-ones with N -(arylsulfonyl)acrylamides has been reported via a 1,5-hydrogen atom transfer (HAT), 1,4-aryl migration, and SO2-extrusion sequence.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00434a
Citations
6
Primary Topic
Oxidative Organic Chemistry Reactions
Type
article
Field-Weighted Citation Impact
5.62
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article

A photocatalytic hydrogen atom transfer and aryl migration strategy for the arylalkylation of activated alkenes with 1-(o-iodoaryl)-alkan-1-ones

Shuang Wu, Yan-Lin Chu, Jin‐Heng Li, Liang Zeng et al.
6 citations
Organic Chemistry Frontiers
Oxidative Organic Chemistry Reactions
5.62
article

A photocatalytic hydrogen atom transfer and aryl migration strategy for the arylalkylation of activated alkenes with 1-(o-iodoaryl)-alkan-1-ones

Shuang Wu, Yan-Lin Chu, Jin‐Heng Li, Liang Zeng, Jie Yang, Ming Hu
article en
6 citations

Abstract

A visible-light catalyzed strategy for remote C(sp3)–H alkylation of 1-( o -iodoaryl)alkan-1-ones with N -(arylsulfonyl)acrylamides has been reported via a 1,5-hydrogen atom transfer (HAT), 1,4-aryl migration, and SO2-extrusion sequence.

Organic Chemistry FrontiersVol. 12(16)
Qingdao University of Science and Technology (CN), Henan Normal University (CN), Lanzhou University (CN)
Openalex Percentile: Top 4%
Oxidative Organic Chemistry Reactions
5.62
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