Droplet velocity in both limits of low and high soluble surfactants in a Hele-Shaw cell: experimental and analytical results

The transport of droplets in microfluidic channels is strongly dominated by interfacial properties, which makes it a relevant tool for understanding the mechanisms associated with the presence of more or less soluble surfactants. In this paper, we show that the mobility of an oil droplet pushed by an aqueous carrier phase in a Hele-Shaw cell qualitatively depends on the nature of the surfactants: the drop velocity is an increasing function of the drop radius for highly soluble surfactants, whereas it is a decreasing function for poorly soluble surfactants. These two different behaviours are experimentally observed by using two families of surfactant with a carbon chain of variable length. We first focus on the second regime, observed here for the first time, and we develop a model which takes into account the flux of surfactants on the whole droplet interface, assuming an incompressible surfactant monolayer. This model leads to a quantitative agreement with the experimental data, without any adjustable parameter. We then propose a model for a stress-free interface, i.e. for highly soluble surfactants. In these two limits, the models become independent on the physico-chemical properties of the surfactants, and should be valid for any surfactant complying with the incompressible or stress-free limit. As such, we provide a theoretical framework with two limits for all the experimental physico-chemical configurations, which constitute the bounds for the droplet mobility for intermediate surfactant solubility.