A metal–organic framework-derived α-MnS/MWCNT composite as a promising pseudocapacitive material for a flexible quasi-solid-state asymmetric supercapacitor device

The low conductivity of traditionally used pseudocapacitive materials like transition metal oxides has forced researchers to look for alternative materials. Transition metal sulfides are being investigated as viable alternative materials and have shown promising results. In this work, an α-MnS/MWCNT composite is selected as the active material for supercapacitor application. α-MnS has better conductivity than many transition metal oxides but has an extremely low specific surface area (10.5 m² g^-1), which reduces its specific capacitance. Metal-organic framework (MOF)-derived materials are known to possess higher specific surface area and favorable pore size distribution. Herein, α-MnS/MWCNT composites are synthesized <i>via</i> two routes: the conventional solvothermal technique and the MOF route, and their performance is compared. It is proved that the α-MnS/MWCNT composite synthesized through the MOF route shows a favorable porous structure and better performance than the composite synthesized through the conventional route. It shows a specific surface area of 47.6 m² g^-1 and a specific capacitance of 546.3 F g^-1 at 1 A g^-1 with a mass loading of 1.5 mg cm^-2 in 3 M KOH under a 3-electrode configuration. A flexible quasi-solid-state asymmetric supercapacitor device is fabricated with MOF-derived α-MnS/MWCNT as the positive electrode material, and the device achieved a potential window of 1.4 V, a specific capacitance of 82.5 F g^-1 at 1 A g^-1 and a capacitance retention of 90.1% after 5000 cycles at 10 A g^-1. The results clearly indicate that transition metal sulfides like MOF-derived α-MnS can be a viable alternative to traditional materials like transition metal oxides. The assembled device has the potential to power flexible, wearable electronics.