<i>Ortho</i>-Hydroxy-Substituted Diaryliodonium Salts Enabled Intramolecular Aryliodonium Rearrangement in Synthesis of <i>Ortho</i>-Iodo Diaryl Ethers
A new family of <i>ortho</i>-hydroxy-substituted diaryliodonium salts was synthesized with 1-acetoxy-2-iodobenzenes, in which the acetyl group was cleaved in a one-pot synthesis. The <i>ortho</i>-hydroxyl-substituted diaryliodonium salts underwent further intramolecular aryl migration reaction, giving <i>ortho</i>-iodo diaryl ethers either with or without the presence of bases.
Authors
- Jianwei Han (ORCID: https://orcid.org/0000-0002-8354-5684)
- Zhen‐Jiang Xu (ORCID: https://orcid.org/0000-0003-3574-917X)
- Limin Wang (ORCID: https://orcid.org/0000-0002-4025-5361)
- Cheng Pan
- Taiyou Liu
Institutions
- East China University of Science and Technology (CN)
- Chinese Academy of Sciences (CN)
- Shanghai Institute of Organic Chemistry (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2025-04-15
- DOI
- https://doi.org/10.1021/acs.joc.4c03179
- Citations
- 3
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 2.81
Funders
- National Natural Science Foundation of China