Emergent facilitation by random constraints in a facilitated random walk model of glass

The physics of glass has been a significant topic of interest for decades. Dynamical facilitation is widely believed to be an important characteristic of glassy dynamics, but the precise mechanism is still under debate. We propose a lattice model of glass called the facilitated random walk (FRW). Each particle performs a continuous time random walk in the presence of its own random local kinetic constraints. The particles do not interact energetically. Instead, they interact kinetically with a hopping rate resampling rule under which motions of a particle can randomly perturb the local kinetic constraints of other particles. This dynamic interaction is reversible, following a rate restoration rule. A step-by-step reversal of the particle motions exactly restores the previous constraints, modeling randomness quenched in the configuration space of glass. The model exhibits stretched exponential relaxation and dynamical heterogeneity typical of glasses. Despite the lack of an explicit facilitation rule, the FRW shows facilitation behaviors closely analogous to those of the kinetically constrained models (KCM). The FRW is a coarse-grained version of the distinguishable particle lattice model (DPLM) and this exemplifies that compatible defect and atomistic models can complement each other in the study of glass.

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Publication Details

Journal
Physical review. E
Published
2025-04-14
DOI
https://doi.org/10.1103/physreve.111.044120
Primary Topic
Computer Graphics and Visualization Techniques
Type
article
Field-Weighted Citation Impact
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article

Emergent facilitation by random constraints in a facilitated random walk model of glass

Haihui Ruan, Chi‐Hang Lam, Hai-Yao Deng, Chu Xiao et al.
Physical review. E
Computer Graphics and Visualization Techniques
article

Emergent facilitation by random constraints in a facilitated random walk model of glass

Haihui Ruan, Chi‐Hang Lam, Hai-Yao Deng, Chu Xiao, Weibing Zhang, Chun-Shing Lee, Udoka Nwankwo, Cho-Tung Yip, Leo S. I. Lam
article en

Abstract

The physics of glass has been a significant topic of interest for decades. Dynamical facilitation is widely believed to be an important characteristic of glassy dynamics, but the precise mechanism is still under debate. We propose a lattice model of glass called the facilitated random walk (FRW). Each particle performs a continuous time random walk in the presence of its own random local kinetic constraints. The particles do not interact energetically. Instead, they interact kinetically with a hopping rate resampling rule under which motions of a particle can randomly perturb the local kinetic constraints of other particles. This dynamic interaction is reversible, following a rate restoration rule. A step-by-step reversal of the particle motions exactly restores the previous constraints, modeling randomness quenched in the configuration space of glass. The model exhibits stretched exponential relaxation and dynamical heterogeneity typical of glasses. Despite the lack of an explicit facilitation rule, the FRW shows facilitation behaviors closely analogous to those of the kinetically constrained models (KCM). The FRW is a coarse-grained version of the distinguishable particle lattice model (DPLM) and this exemplifies that compatible defect and atomistic models can complement each other in the study of glass.

Physical review. EVol. 111(4)
Hong Kong Polytechnic University (HK), Harbin Institute of Technology (CN), Changsha University of Science and Technology (CN), Cardiff University (GB)
Openalex Percentile: Top 87%
Computer Graphics and Visualization Techniques
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