A mixed-linker strategy in covalent organic frameworks for enhanced sunlight-driven photocatalytic oxidation activity and stability

We present a simple mixed-linker strategy to enhance the photocatalytic oxidation activity and stability of covalent organic framework semiconductors. The TpTfbPa-COF, featuring an unconventional reversed AA-stacking structure with both imine and ketoamine linkages, exhibits excellent structural stability and superior photocatalytic performance compared to the fully imine-linked TfbPa-COF and the fully ketoamine-linked TpPa-COF.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc01192b
Citations
10
Primary Topic
Covalent Organic Framework Applications
Type
article
Field-Weighted Citation Impact
5.18
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article

A mixed-linker strategy in covalent organic frameworks for enhanced sunlight-driven photocatalytic oxidation activity and stability

Jikuan Qiu, Wenrui Wan, Tingting Fan, Xiaoxin Tian et al.
10 citations
Chemical Communications
Covalent Organic Framework Applications
5.18
article

A mixed-linker strategy in covalent organic frameworks for enhanced sunlight-driven photocatalytic oxidation activity and stability

Jikuan Qiu, Wenrui Wan, Tingting Fan, Xiaoxin Tian, Yuling Zhao, Zhiyong Li, Xiangxin Xue, Kexi Zhang, Huiyong Wang
article en
10 citations

Abstract

We present a simple mixed-linker strategy to enhance the photocatalytic oxidation activity and stability of covalent organic framework semiconductors. The TpTfbPa-COF, featuring an unconventional reversed AA-stacking structure with both imine and ketoamine linkages, exhibits excellent structural stability and superior photocatalytic performance compared to the fully imine-linked TfbPa-COF and the fully ketoamine-linked TpPa-COF.

Chemical CommunicationsVol. 61(40)
Xinxiang University (CN), Henan Normal University (CN)
Openalex Percentile: Top 4%
Covalent Organic Framework Applications
5.18
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A mixed-linker strategy in covalent organic frameworks for enhanced sunlight-driven photocatalytic oxidation activity and stability — Jikuan Qiu, Wenrui Wan, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS