Controllable atom transfer enables photoredox-catalyzed defluorinative alkylation of trifluoromethyl alkenes with polychloroalkanes
A general and mild protocol for the selective activation of C–H and C–Cl bonds in polychloroalkanes via switchable atom transfer processes under photoredox catalysis is presented, enabling the defluorinative alkylation of α-trifluoromethyl alkenes.
Authors
- Mu-Xiang Chen
- Yi‐Long Zhu (ORCID: https://orcid.org/0000-0001-6923-0275)
- Zhenhua Jia (ORCID: https://orcid.org/0000-0002-5154-4839)
- Xu‐Hong Hu (ORCID: https://orcid.org/0000-0001-6584-2901)
- Xuefei Zhao (ORCID: https://orcid.org/0000-0003-2314-1431)
- Ziyan Wang
- Xin-Lu Fan
Institutions
- Nanjing Tech University (CN)
- Fudan University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00369e
- Citations
- 1
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.79