Extraction of Copper from Printed Circuit Boards in an Alkaline Solution Using EDTA

With the rapid technological development in the 21st century, the increasing consumption of electronic devices has led to a rise in the generation of waste electrical and electronic equipment (WEEE) due to the disposal of equipment considered obsolete. A significant portion of these wastes contain printed circuit boards (PCBs), which serve as substrates for the connection of microchips, resistors, capacitors, and other components. These boards are composed of various materials, primarily metals such as copper. Thus, this study investigated the recovery of copper from PCB waste (WPCBs) from computers through alkaline leaching, using EDTA and hydrogen peroxide at temperatures of 40 °C, 60 °C, and 80 °C, with a concentration of 0.6 mol/L and varying particle sizes. Using a UV-VIS spectrophotometer, it was observed that the copper extraction process with EDTA at 0.6 mol/L and a temperature of 60 °C achieved a recovery rate of 78.6% for particles smaller than 0.177 mm after 180 min, following the Avrami kinetic model. The results highlight the potential of EDTA as a complexing agent in copper extraction, positioning it as a promising technique to reduce environmental contamination and recover strategic resources through urban mining through the recovery of metals from WEEE.

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Publication Details

Journal
Minerals
Published
2025-04-13
DOI
https://doi.org/10.3390/min15040409
Primary Topic
Recycling and Waste Management Techniques
Type
article
Field-Weighted Citation Impact
0.00

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Extraction of Copper from Printed Circuit Boards in an Alkaline Solution Using EDTA

Hugo Marcelo Veit, Tácia Costa Veloso, Tatiane Benvenuti, Alan Oliveira Goulart
Minerals
Recycling and Waste Management Techniques
article

Extraction of Copper from Printed Circuit Boards in an Alkaline Solution Using EDTA

Hugo Marcelo Veit, Tácia Costa Veloso, Tatiane Benvenuti, Alan Oliveira Goulart
article en

Abstract

With the rapid technological development in the 21st century, the increasing consumption of electronic devices has led to a rise in the generation of waste electrical and electronic equipment (WEEE) due to the disposal of equipment considered obsolete. A significant portion of these wastes contain printed circuit boards (PCBs), which serve as substrates for the connection of microchips, resistors, capacitors, and other components. These boards are composed of various materials, primarily metals such as copper. Thus, this study investigated the recovery of copper from PCB waste (WPCBs) from computers through alkaline leaching, using EDTA and hydrogen peroxide at temperatures of 40 °C, 60 °C, and 80 °C, with a concentration of 0.6 mol/L and varying particle sizes. Using a UV-VIS spectrophotometer, it was observed that the copper extraction process with EDTA at 0.6 mol/L and a temperature of 60 °C achieved a recovery rate of 78.6% for particles smaller than 0.177 mm after 180 min, following the Avrami kinetic model. The results highlight the potential of EDTA as a complexing agent in copper extraction, positioning it as a promising technique to reduce environmental contamination and recover strategic resources through urban mining through the recovery of metals from WEEE.

MineralsVol. 15(4)
Universidade Federal do Rio Grande do Sul (BR), Universidade de São Paulo (BR), Universidade Estadual de Santa Cruz (BR), Universidade Federal do Sul da Bahia (BR)
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Conselho Nacional de Desenvolvimento Científico e Tecnológico, Universidade Federal do Rio Grande do Sul, Fundação de Desenvolvimento da Pesquisa, Universidade Estadual de Santa Cruz, Division of Graduate Education
Openalex Percentile: Top 91%
Recycling and Waste Management Techniques
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