Insights for controlling plutonium behavior in hydrochloric acid solutions
Cyclic voltammetry, UV-vis, and X-ray absorption spectroscopy were used to demonstrate that aqueous plutonium coordination chemistry and electron transfer reactivity can be controlled by judicious manipulation of hydrochloric acid concentrations.
Authors
- Sara L. Adelman (ORCID: https://orcid.org/0000-0001-7989-3451)
- Natalie T. Rice (ORCID: https://orcid.org/0000-0002-6233-7958)
- Manuel Luca Besmer (ORCID: https://orcid.org/0000-0003-4768-0149)
- Julia G. Knapp (ORCID: https://orcid.org/0000-0002-3324-4875)
- Molly M. MacInnes (ORCID: https://orcid.org/0000-0001-9513-7402)
- James C. Gilhula (ORCID: https://orcid.org/0000-0001-6300-2570)
- Kelly E. Aldrich (ORCID: https://orcid.org/0000-0001-6192-2672)
- Jan Klouda (ORCID: https://orcid.org/0000-0003-3564-6189)
- Brian N. Long (ORCID: https://orcid.org/0000-0003-4410-4509)
- Travis Marshall-Roth (ORCID: https://orcid.org/0000-0002-6245-6404)
- Stosh A. Kozimor (ORCID: https://orcid.org/0000-0001-7387-0507)
- Brian T. Arko (ORCID: https://orcid.org/0000-0002-9268-8839)
- Ida Piedmonte
- Yufei Wang (ORCID: https://orcid.org/0000-0002-5780-112X)
- Christopher J. Godt
- Alexandra L. Nagelski
Institutions
- Los Alamos National Laboratory (US)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00409h
- Primary Topic
- Radioactive element chemistry and processing
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- U.S. Department of Energy
- Glenn T. Seaborg Institute
- Office of Science
- National Nuclear Security Administration
- Basic Energy Sciences
- Laboratory Directed Research and Development
- Los Alamos National Laboratory
- SLAC National Accelerator Laboratory