Regulating photochromic behavior of a cyanostilbene by cucurbit[<i>n</i>]uril hosts in aqueous solution

The effects of cucurbit[<i>n</i>]uril (CB[<i>n</i>]) hosts on the photochromic behaviors of a cyanostilbene derivative (1-Z) are reported. We find that CB[7] favors the <i>Z</i> to <i>E</i> isomerization and CB[8] inhibits the photoreaction of 1-Z. Interestingly, CB[10] induces an emission color change by encapsulating the photodimer of 1-Z in its cavity during irradiation.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc00182j
Citations
1
Primary Topic
Photochromic and Fluorescence Chemistry
Type
article
Field-Weighted Citation Impact
0.52
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Regulating photochromic behavior of a cyanostilbene by cucurbit[n]uril hosts in aqueous solution

Xin Huang, Xie Han, Fangwei Wu, Simin Liu et al.
1 citations
Chemical Communications
Photochromic and Fluorescence Chemistry
0.52
article

Regulating photochromic behavior of a cyanostilbene by cucurbit[n]uril hosts in aqueous solution

Xin Huang, Xie Han, Fangwei Wu, Simin Liu, Chunmei Wang, Zengyan Xia
article en
1 citations

Abstract

The effects of cucurbit[<i>n</i>]uril (CB[<i>n</i>]) hosts on the photochromic behaviors of a cyanostilbene derivative (1-Z) are reported. We find that CB[7] favors the <i>Z</i> to <i>E</i> isomerization and CB[8] inhibits the photoreaction of 1-Z. Interestingly, CB[10] induces an emission color change by encapsulating the photodimer of 1-Z in its cavity during irradiation.

Chemical CommunicationsVol. 61(40)
Wuhan University of Science and Technology (CN)
Clean water and sanitation
Openalex Percentile: Top 40%
Photochromic and Fluorescence Chemistry
0.52
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