Synergistic enhancement of DSSC performance via Ti3C2 MXene-modified copper redox electrolytes: Mechanistic insights into charge transfer and recombination

The incorporation of Ti 3 C 2 MXene micro-nano sheets into a copper complex redox mediator electrolyte resulted in significant improvements in charge transport and recombination suppression for dye-sensitized solar cells (DSSCs). The device fabricated using the incorporation of Ti 3 C 2 MXene at an optimized loading of 0.5 wt% in the copper complex redox mediator electrolyte reached a champion power conversion efficiency (PCE) of 7.45 % under 1-Sun illumination. This performance enhancement is attributed to MXene's high electrical conductivity and its effective passivation of trap states, which collectively bolster charge transport and dye regeneration in DSSCs. These findings underscore the transformative potential of well-dispersed MXene micro-nanosheets to synergistically improve ionic conductivity and reduce recombination losses in copper complex redox mediators. X-ray diffraction analysis proved that Cu complex engagement with MXene also enhances the layering structure of MXenes. Mechanistic studies via electrochemical impedance spectroscopy and intensity-modulated spectroscopies indicate that the MXene-modified electrolyte reduces back-recombination losses by 14.20 % and extends carrier lifetimes. Under 10 % sunlight, the device maintains a PCE of 12.51 %, underscoring its potential for low-light Internet-of-Things (IoT) applications. These findings open a pathway for engineering MXenes in advanced electrolytes to achieve synergistic improvements in the stability and performance of DSSCs. • Ti 3 C 2 MXene is incorporated into the [Cu(dmp) 2 ] 2+/+ liquid redox shuttle. • MXene significantly improves charge transport and recombination suppression. • MXene-modified electrolyte increases R rec by 14.20 % and extends carrier lifetimes. • The MXene-modified electrolyte device achieved 12.51 % of PCE under 10 % sunlight.