Influence of second metal incorporation on nickel-based unsupported catalysts for CO2 reduction (CO2-SR) Technology

• Highly innovative dual function Ni-M ( M = Ba, Ca, K or Sr) catalytic materials were developed for CO 2 storage and conversion. • Second metal alters the CO 2 -SR performance under high-temperature operation. • Ni-M catalytic materials can facilitate the production of syn gas from industrial flue gas emissions. The incorporation of alkali or alkaline-earth metals in unsupported Ni-based catalyst was analyzed as a strategy for high-temperature CO 2 storage and chemical regeneration via methane, within the framework of CO 2 storage–regeneration (CO 2 -SR) technology. It was observed that the addition of Ba, Ca, Sr and K into the Ni-catalyst modifies not only the textural but also the electronic properties of the catalysts. A restructuring of the unsupported oxide surface occurs by the reduction of the modified Ni-oxide catalyst when exposed to a H 2 -atmosphere at high temperature (600 °C). Upon oxygen release from NiO lattice, the alkali metals favor the reduction and stabilization of these Ni-metallic species. In such a way, nickel-metallic particles are formed from the NiO-bulk, thus generating unsupported metal catalysts; stabilized by interaction with alkali metals and anchored on the surface. The presence of Ba, Ca, Sr or K in the Ni-based catalyst formulation influences the CO 2 storage capacity and regeneration by conversion employing CH 4 registering the trend Ca>Ba> K >Sr for the catalytic activity at 600 °C in term of CO 2 removal capacity and CH 4 conversion.