Spin-state modulation by host–guest chemistry with cucurbiturils
The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(II)-terpyridine complex shifts the spin equilibrium to the low-spin state (Δ<i>T</i><sub>1/2</sub> = 77 K) <i>via</i> secondary coordination sphere perturbations.
Authors
- Meng Yu (ORCID: https://orcid.org/0000-0001-7570-5695)
- Jun Tao (ORCID: https://orcid.org/0000-0003-0610-4305)
- Jie‐Sheng Hu
- Alyona A. Starikova (ORCID: https://orcid.org/0000-0001-5842-0559)
- Xinli Shi (ORCID: https://orcid.org/0000-0002-4443-608X)
- Zhikun Liu (ORCID: https://orcid.org/0000-0002-3770-9553)
- Yu-Xiao Chen (ORCID: https://orcid.org/0000-0002-8594-3619)
- Ke Lu
Institutions
- Beijing Institute of Technology (CN)
- Southern Federal University (RU)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00979k
- Primary Topic
- Physics of Superconductivity and Magnetism
- Type
- article
- Field-Weighted Citation Impact
- 0.00