Expanding Horizons: Taking Advantage of Graphene’s Surface Area for Advanced Applications

Graphene, being a two-dimensional monolayer of carbon, exhibits an exceptionally increased surface-to-volume ratio due to its atomic thinness and high aspect ratio, making it a material of considerable interest in advanced technology applications. Recent developments have leveraged their unique surface characteristics, such as nanoscale ripples and grooves, to enhance energy storage, sensing, catalysis, and environmental remediation performance. Its extensive surface area enables rapid ion adsorption and desorption, significantly improving energy and power densities in supercapacitors and lithium-ion batteries while enhancing stability over prolonged cycles. In sensing, the high surface-to-volume ratio supports the immobilization of biomolecules and nanoparticles, improving sensitivity in detecting gases, biomarkers, and pollutants, thereby advancing diagnostic and environmental monitoring applications. Its expansive surface area and unique electronic properties contribute to high catalytic efficiencies, enabling sustainable chemical processes, such as hydrogen production, water treatment, and pollutant degradation. Unlike many review articles that primarily explore the functionalization of graphene, this study mainly emphasizes the evaluation of methodologies aimed at augmenting graphene’s surface area. This review systematically evaluates recent advancements in the optimization of graphene surface characteristics, with a primary focus on their role in enhancing energy storage systems while also addressing emerging applications in healthcare and environmental sustainability.