2D Aza-COF-Supported Ruthenium Complex: A Recyclable Auto-Tandem Catalyst for the Preparation of Quinazolinones from Allylic Alcohols and <i>o</i>-Aminobenzamides
Ruthenium complex Ru(<i>p-</i>cymene)@Aza-COF was synthesized by the immobilization of [Ru(<i>p-</i>cymene)Cl][Cl] on a 2D Aza-COF. Then, this complex was utilized as an auto-tandem catalyst for the preparation of quinazolinones from allylic alcohols and <i>o</i>-aminobenzamides via redox isomerization/acceptorless dehydrogenative coupling. More importantly, its catalytic activity is well maintained during six runs.
Authors
- Wei Zhao (ORCID: https://orcid.org/0000-0002-0076-2510)
- Qixun Shi (ORCID: https://orcid.org/0000-0002-4924-831X)
- Xiaozhong Chen (ORCID: https://orcid.org/0000-0001-8601-1445)
- Shouhai Zhang (ORCID: https://orcid.org/0000-0002-1533-7402)
- Feng Li (ORCID: https://orcid.org/0000-0003-3288-4069)
- Xiaoting Wang
- Yong Xu (ORCID: https://orcid.org/0000-0002-0891-7863)
Institutions
- Nanjing Tech University (CN)
- Dalian University of Technology (CN)
- Nanjing University of Science and Technology (CN)
- Institute of Organic Synthesis (RU)
- State Key Laboratory of Fine Chemicals
Publication Details
- Journal
- Organic Letters
- Published
- 2025-04-09
- DOI
- https://doi.org/10.1021/acs.orglett.5c00529
- Citations
- 2
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.07
Funders
- National Natural Science Foundation of China