Cover Feature: Technetium and Rhenium Auto‐reduction, Polymerization and Lability towards Group VII Polyoxometalate Chemistry (Chem. Eur. J. 21/2025)
The hand you are dealt: Reduced TcV/ReVI octahedra and fully oxidized TcVII/ReVII tetrahedra self-assemble, mix and match, and exchange to produce the first group VII technetium/rhenium mixed metal polyoxometalate and the first rigorous characterization of a rhenium autoreduction product. Based on both the lability of the polynuclear clusters and trends in reduction, the expansion of nascent group VII polyoxometalates is promising. More information can be found in the Research Article by M. Nyman and co-workers (DOI: 10.1002/chem.202404144).
Authors
- Carles Bó (ORCID: https://orcid.org/0000-0001-9581-2922)
- Jordi Buils (ORCID: https://orcid.org/0000-0002-2674-6551)
- Mireia Segado (ORCID: https://orcid.org/0000-0002-1290-6403)
- Jenna Bustos (ORCID: https://orcid.org/0000-0002-8016-5619)
- May Nyman (ORCID: https://orcid.org/0000-0002-1787-0518)
- Mohammad Shohel (ORCID: https://orcid.org/0000-0003-2736-2389)
- Ana Guilherme Buzanich (ORCID: https://orcid.org/0000-0001-5543-9924)
- Lev N. Zakharov (ORCID: https://orcid.org/0000-0003-3340-4645)
Institutions
- Oregon State University (US)
- Federal Institute For Materials Research and Testing (DE)
- Institut Català d'Investigació Química (ES)
- Universitat Rovira i Virgili (ES)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-04-09
- DOI
- https://doi.org/10.1002/chem.202582104
- Primary Topic
- Polyoxometalates: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00