Evidence for reduced periodic lattice distortion within the Sb-terminated surface layer of the kagome metal <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mrow><mml:mi>CsV</mml:mi></mml:mrow><mml:mn>3</mml:mn></mml:msub><mml:
The discovery of the kagome metal <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:msub><a:mrow><a:mi>CsV</a:mi></a:mrow><a:mn>3</a:mn></a:msub><a:msub><a:mrow><a:mi>Sb</a:mi></a:mrow><a:mn>5</a:mn></a:msub></a:math> sparked broad interest, due to the coexistence of a charge density wave (CDW) phase and possible unconventional superconductivity in the material. In this Letter, we use low-energy electron diffraction (LEED) with a <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"><b:mi>µ</b:mi><b:mi mathvariant="normal">m</b:mi></b:math>-sized electron beam to explore the periodic lattice distortion at the antimony-terminated surface in the CDW phase. We recorded high-quality backscattering diffraction patterns in ultrahigh vacuum from multiple cleaved samples. Unexpectedly, we did not find superstructure reflexes at intensity levels predicted from dynamical LEED calculations for the reported <d:math xmlns:d="http://www.w3.org/1998/Math/MathML"><d:mrow><d:mn>2</d:mn><d:mo>×</d:mo><d:mn>2</d:mn><d:mo>×</d:mo><d:mn>2</d:mn></d:mrow></d:math> bulk structure. Our results suggest that in <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"><e:msub><e:mrow><e:mi>CsV</e:mi></e:mrow><e:mn>3</e:mn></e:msub><e:msub><e:mrow><e:mi>Sb</e:mi></e:mrow><e:mn>5</e:mn></e:msub></e:math> the periodic lattice distortion accompanying the CDW is less pronounced at Sb-terminated surfaces than in the bulk.
Authors
- I. Vinograd (ORCID: https://orcid.org/0000-0002-1054-3741)
- Claus Ropers (ORCID: https://orcid.org/0000-0002-9539-3817)
- Felix Kurtz (ORCID: https://orcid.org/0000-0003-0811-5200)
- Amir A. Haghighirad (ORCID: https://orcid.org/0000-0003-4723-4966)
- Chandra Shekhar (ORCID: https://orcid.org/0000-0002-3330-0400)
- Alp Akbıyık (ORCID: https://orcid.org/0000-0003-2600-4379)
- M. Le Tacon (ORCID: https://orcid.org/0000-0002-5838-3724)
- Gevin von Witte (ORCID: https://orcid.org/0000-0003-3698-9829)
- Claudia Felser (ORCID: https://orcid.org/0000-0002-8200-2063)
- Dong Chen (ORCID: https://orcid.org/0000-0002-7170-9725)
- Lukas Jehn
Institutions
- Karlsruhe Institute of Technology (DE)
- ETH Zurich (CH)
- Institute for Biomedical Engineering (CH)
- Max Planck Institute for Chemical Physics of Solids (DE)
- Max Planck Institute for Multidisciplinary Sciences (DE)
- University of Göttingen (DE)
Publication Details
- Journal
- Physical review. B./Physical review. B
- Published
- 2025-04-09
- DOI
- https://doi.org/10.1103/physrevb.111.l140101
- Citations
- 3
- Primary Topic
- Topological Materials and Phenomena
- Type
- article
- Field-Weighted Citation Impact
- 3.74
Funders
- Deutsche Forschungsgemeinschaft
- Max Planck School of Photonics
- European Research Council