Azadiene‐Linked Carbon‐Organic Frameworks for Enhanced Photocatalytic Efficiency in Organic Synthesis
2D covalent organic frameworks (2D-COFs) have garnered huge attention as a promising platform for solar to chemical energy conversion. In this work, two novel azadiene-linked COFs (COF-JLU236 and COF-JLU237) were designed and successfully synthesized under solvothermal conditions for the first time. And new materials have high crystallinity, large surface area, good durability, and broad absorption range, as well as excellent photoelectric properties. Importantly, they can effectively induce selective oxidation of sulfides and phenylboronic acids under visible light, and show wide substrate adaptability and superior reusability.
Authors
- Shanshan Zhu (ORCID: https://orcid.org/0000-0002-4039-3350)
- Huijuan Yue (ORCID: https://orcid.org/0000-0001-8410-7443)
- Xiaoming Liu (ORCID: https://orcid.org/0000-0001-5736-7282)
- Xiao Xiao (ORCID: https://orcid.org/0000-0001-5070-9577)
- Yuxin Hou
Institutions
- Jilin University (CN)
- Jilin Medical University (CN)
- Jilin Agricultural University (CN)
- Ulsan National Institute of Science and Technology (KR)
- Changchun University (CN)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-04-09
- DOI
- https://doi.org/10.1002/chem.202500934
- Citations
- 4
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.07
Funders
- Natural Science Foundation of Jilin Province
- National Natural Science Foundation of China
- People's Government of Jilin Province
- State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University