Heterospin molecular complexes of Cu(hfac)<sub>2</sub> with pyridyl-substituted nitronyl nitroxides: peculiarities of structure and magnetic properties

Cu( ii ) complexes based on pyridyl-substituted nitroxides with a centrosymmetric binuclear fragment were synthesized and studied. Bulky and rigid substituents in the nitroxide molecule facilitate the implementation of a spin transition in complexes.

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Publication Details

Journal
New Journal of Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5nj00967g
Primary Topic
Magnetism in coordination complexes
Type
article
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article

Heterospin molecular complexes of Cu(hfac)2 with pyridyl-substituted nitronyl nitroxides: peculiarities of structure and magnetic properties

S.E. Tolstikov, A.S. Bogomyakov, Г.В. Романенко, В.И. Овчаренко et al.
New Journal of Chemistry
Magnetism in coordination complexes
article

Heterospin molecular complexes of Cu(hfac)2 with pyridyl-substituted nitronyl nitroxides: peculiarities of structure and magnetic properties

S.E. Tolstikov, A.S. Bogomyakov, Г.В. Романенко, В.И. Овчаренко, Gleb Letyagin, Andrey Kolesnikov, Kristina A. Smirnova
article en

Abstract

Cu( ii ) complexes based on pyridyl-substituted nitroxides with a centrosymmetric binuclear fragment were synthesized and studied. Bulky and rigid substituents in the nitroxide molecule facilitate the implementation of a spin transition in complexes.

New Journal of ChemistryVol. 49(18)
Novosibirsk State University (RU), N.D. Zelinsky Institute of Organic Chemistry (RU), International Tomography Center (RU)
Openalex Percentile: Top 96%
Magnetism in coordination complexes
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Heterospin molecular complexes of Cu(hfac)<sub>2</sub> with pyridyl-substituted nitronyl nitroxides: peculiarities of structure and magnetic properties — S.E. Tolstikov, A.S. Bogomyakov, et al. · New Journal of Chemistry (2025) | TGRS Research Map | TGRS