Nickel-Catalyzed Nucleophilic Substitution of Cyclopropenes by Secondary Phosphines
Abstract Research on the efficient synthesis of allylphosphine compounds is of crucial significance. Herein, a nickel-catalyzed ring-opening of cyclopropenes is described to synthesize allylphosphine compounds. This transformation enables a mild and efficient preparation of allylphosphine compounds in good yields, with 100% atom efficiency.
Authors
- Yicong Qi (ORCID: https://orcid.org/0009-0005-5634-7649)
- Haisheng Fang (ORCID: https://orcid.org/0000-0002-1600-2946)
- Liyan Yuwen
- Qing‐Wei Zhang (ORCID: https://orcid.org/0000-0002-8577-6304)
- Jingwen Wang (ORCID: https://orcid.org/0009-0002-6495-0884)
Institutions
- University of Science and Technology of China (CN)
Publication Details
- Journal
- Synlett
- Published
- 2025-04-09
- DOI
- https://doi.org/10.1055/a-2579-3319
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China