Directing Group-Integrated Poly(phenylene sulfide): Achieving Chemical Stability and Controlled Degradability
Plastic sustainability necessitates catalytic technologies for disassembling polymers into monomers or their precursors. We report herein directing group-integrated poly(phenylene sulfide)s, which can be converted into monomer precursors via nickel-catalyzed site-selective C–S bond cleavage. These polymers exhibit excellent chemical and thermal stability. The crystallinity of the polymers is tunable by the design of the directing group.
Authors
- Mamoru Tobisu (ORCID: https://orcid.org/0000-0002-8415-2225)
- Hiroshi Uyama (ORCID: https://orcid.org/0000-0002-8587-2507)
- Namiki Takenaka
- Yu‐I Hsu (ORCID: https://orcid.org/0000-0002-4533-7200)
- Satoshi Ogawa (ORCID: https://orcid.org/0000-0002-4801-970X)
Institutions
- Center for Research and Interdisciplinarity (FR)
- Graduate School USA (US)
- The University of Osaka (JP)
Publication Details
- Journal
- Macromolecules
- Published
- 2025-04-09
- DOI
- https://doi.org/10.1021/acs.macromol.5c00051
- Primary Topic
- Conducting polymers and applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Ministry of Education, Culture, Sports, Science and Technology
- Japan Society for the Promotion of Science