Effect of Applied Current on Tribological Properties of Polyphenyl Ether

The widespread adoption of electric vehicles (EVs) has introduced new challenges in drivetrain lubrication, particularly concerning electrical corrosion, frictional wear, and hydrogen embrittlement. While polyalphaolefin (PAO)-based lubricants are commonly used, they struggle under high-speed and high-torque conditions. In contrast, polyphenyl ether (PPE)-based lubricants offer superior wear resistance and effectively suppress hydrogen generation, making them promising for EV applications. This study examines the effects of current direction and magnitude on tribofilm formation and frictional behavior in a PPE-lubricated environment. The results show that PPE exhibits unique tribofilm adhesion characteristics influenced by electrical conditions, unlike PAO. Surface analysis reveals that the tribofilm mainly consists of amorphous carbon, and friction under an electrical bias induces PPE oxidation, with oxidation products forming more readily at the positive electrode. Tribofilm formation correlated with increased friction and wear, particularly under currents of 10 mA or higher. Although PPE is more sensitive to electrical influences than PAO, it exhibits excellent wear resistance and maintains a low coefficient of friction even under electrification. This suggests that PPE could be suitable for lubrication in electrical environments and may serve as a promising lubricant for EV drive systems and similar applications.