Discrimination of Slight Thermal Damage to Fibers for Arson Investigation

ABSTRACT This study explores the forensic potential of thermal damage traces on clothing fibers to identify arsonist. Seven common fiber materials, including cotton, linen, wool, silk, PET, nylon, and/or their blended fabrics, were picked and their thermal properties were analyzed first. A cone calorimeter, the internationally recognized standard heat resource, was applied to simulate transient high‐temperature conditions similar to those in arson cases. Thermogravimetric analysis revealed that silk (270°C), wool (280°C) and cotton (280°C) entered the thermal decomposition stage first, followed by cotton–linen blends (320°C), with the synthetic fibers PET and nylon decomposed from 370°C and 400°C, respectively. Up to 450°C, all fabrics have experienced a mass loss over 50%. Macroscopic and microscopic observations (scanning electron microscopy (SEM)) showed that distinct thermal damage characteristics formed on each kind of fabrics after heating. Cotton fabric began to discolor at around 280°C, with cotton fiber presenting rupture traces due to thermal decomposition observed at 320°C. Similarly, cotton–linen fabric exhibited discoloration at around 320°C, with fiber ruptured due to thermal decomposition at 340°C. Silk fabric began to discolor at around 225°C, with carbonization traces detected by both macroscopically and SEM after heating at 310°C. Wool fabric showed discoloration and shrinkage at about 320°C, with fiber curling, cracking, wrinkling, and expansion observed microscopically. Polyester and polyester–cotton fabrics exhibited wrinkling and shrinkage at around 175°C, with fiber melting at 225°C distinguished microscopically. Nylon fabric showed wrinkling and shrinkage at around 225°C, with fiber melting observed via SEM. This analysis on thermal damage traces offers crucial forensic evidence to determine suspects' proximity to fire, aiding in arson investigations.