The facile preparation of mixed-valence metal–organic frameworks through reduction
A facile strategy was applied to prepare Cu(I)/Cu(II) MOFs, where the Cu(I) amount and porous structure can be adjusted by the degree of reduction and the size of HKUST-1, by partially reducing HKUST-1 with hydrazine hydrate at room temperature. The Cu(I)/Cu(II) MOFs exhibit excellent catalytic capability in the Cu(I)-catalyzed azide alkyne cycloaddition.
Authors
- Yunshi Wang
- Liying Zhang (ORCID: https://orcid.org/0000-0003-3917-0667)
- Cen Chen (ORCID: https://orcid.org/0000-0003-1389-0148)
Institutions
- Northeastern University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00031a
- Primary Topic
- Polyoxometalates: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00