Synthesis of heteropnictogen ligands <i>via</i> P<sup>I</sup> transfer
The heterodipnictogen complexes [{CpMo(CO)<sub>2</sub>}<sub>2</sub>(μ,η<sup>2:2</sup>-PE)] (E = P, As, Sb) react with the phosphorus(I) transfer reagent [(BZIMPY)P][CF<sub>3</sub>SO<sub>3</sub>] (BZIMPY = 2,6-bis(benzimidazole-2-yl)pyridine) in a transmetallation reaction forming the unprecedented [CpMo(CO)<sub>2</sub>(η<sup>3</sup>-P<sub>2</sub>E)] complexes.
Authors
- Lisa Zimmermann
- Michael A. Land (ORCID: https://orcid.org/0000-0001-5861-242X)
- Manfred Scheer (ORCID: https://orcid.org/0000-0003-2182-5020)
- Charles L. B. Macdonald (ORCID: https://orcid.org/0000-0002-0574-1524)
- Christoph Riesinger (ORCID: https://orcid.org/0009-0003-3590-9919)
Institutions
- Dalhousie University (CA)
- University of Regensburg (DE)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01162k
- Citations
- 3
- Primary Topic
- Synthetic Organic Chemistry Methods
- Type
- article
- Field-Weighted Citation Impact
- 2.81