Role of magnetic exchange in catalytic spin effects: insights from nitrite reduction on Co <sub>3</sub> O <sub>4</sub>
We found spin effects especially the magnetic exchange of the substrate have a huge impact on NO 3 RR performance by DFT calculation, and revealed the mechanism of enhanced NO 3 RR activity of low-spin doped Co 3 O 4 from the perspective of spin catalysis.
Authors
- Kin Ho Lo (ORCID: https://orcid.org/0000-0003-0832-0263)
- Junxian Liu (ORCID: https://orcid.org/0000-0002-5873-0095)
- Haoyun Bai (ORCID: https://orcid.org/0000-0002-6504-8561)
- Liangzhi Kou (ORCID: https://orcid.org/0000-0002-3978-117X)
- Di Liu (ORCID: https://orcid.org/0000-0003-3083-6290)
- Hongling Liu (ORCID: https://orcid.org/0009-0004-9803-6745)
- Pan Hui (ORCID: https://orcid.org/0000-0002-1480-5470)
- Shuyang Peng
Institutions
- Queensland University of Technology (AU)
- University of Macau (MO)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta01197c
- Citations
- 3
- Primary Topic
- Ammonia Synthesis and Nitrogen Reduction
- Type
- article
- Field-Weighted Citation Impact
- 1.17