Repulsive thermal van der Waals interaction in multispecies asymmetric electrolytes driven by external electric fields

It is well established that the long-range component of the thermal van der Waals interaction between two semi-infinite dielectrics becomes short-range when an electrolyte is present between them, this is the well known phenomenon of screening. G. Du et al. [Phys. Rev. Lett. 133, 238002 (2024)0031-900710.1103/PhysRevLett.133.238002]. showed that for a binary symmetric electrolyte, an electric field parallel to the dielectric boundaries disrupts screening and a long-range thermal repulsive interaction appears. At large applied fields this long-range repulsive interaction can be explained by the fact that the cations and anions have differing average drifts moving in opposite directions, leading to the correlation of charge density fluctuations between the two species to decouple. Here we extend these results to binary electrolytes which are asymmetric as well as electrolytes with more than two ionic species.

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Publication Details

Journal
Physical review. E
Published
2025-04-07
DOI
https://doi.org/10.1103/physreve.111.044108
Citations
2
Primary Topic
Quantum Electrodynamics and Casimir Effect
Type
article
Field-Weighted Citation Impact
2.49

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article

Repulsive thermal van der Waals interaction in multispecies asymmetric electrolytes driven by external electric fields

Rudolf Podgornik, Guangle Du, David S. Dean, Bing Miao
2 citations
Physical review. E
Quantum Electrodynamics and Casimir Effect
2.49
article

Repulsive thermal van der Waals interaction in multispecies asymmetric electrolytes driven by external electric fields

Rudolf Podgornik, Guangle Du, David S. Dean, Bing Miao
article en
2 citations

Abstract

It is well established that the long-range component of the thermal van der Waals interaction between two semi-infinite dielectrics becomes short-range when an electrolyte is present between them, this is the well known phenomenon of screening. G. Du et al. [Phys. Rev. Lett. 133, 238002 (2024)0031-900710.1103/PhysRevLett.133.238002]. showed that for a binary symmetric electrolyte, an electric field parallel to the dielectric boundaries disrupts screening and a long-range thermal repulsive interaction appears. At large applied fields this long-range repulsive interaction can be explained by the fact that the cations and anions have differing average drifts moving in opposite directions, leading to the correlation of charge density fluctuations between the two species to decouple. Here we extend these results to binary electrolytes which are asymmetric as well as electrolytes with more than two ionic species.

Physical review. EVol. 111(4)
Université de Bordeaux (FR), Chinese Academy of Sciences (CN), Kavli Institute for Theoretical Sciences (CN), University of Chinese Academy of Sciences (CN)
Agence Nationale de la Recherche, National Natural Science Foundation of China, European Research Council, Fundamental Research Funds for the Central Universities
Affordable and clean energy
Openalex Percentile: Top 12%
Quantum Electrodynamics and Casimir Effect
2.49
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Repulsive thermal van der Waals interaction in multispecies asymmetric electrolytes driven by external electric fields — Rudolf Podgornik, Guangle Du, et al. · Physical review. E (2025) | TGRS Research Map | TGRS