ƞ<sup>6</sup>‐Fluoranthene Complexes from the Reactions of Osmacyclopentadienes with Alkynes
Osmacyclopentadiene complexes were obtained from the reactions between OsCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub> and 1,8-dialkynyl naphthalene compounds. These complexes exhibited paramagnetism as they adopted triplet ground states. Reactions of osmacyclopentadienes with alkynes were investigated, which produced novel η<sup>6</sup>-fluoranthene complexes, showing their potential in organometallic synthesis.
Authors
- Yue Zhao (ORCID: https://orcid.org/0000-0002-5710-2994)
- Yue Sun (ORCID: https://orcid.org/0000-0003-3129-5414)
- Wei Bai (ORCID: https://orcid.org/0000-0002-3537-207X)
- Bingjie Fu
- Li Yang (ORCID: https://orcid.org/0000-0001-9298-2029)
- Yan Zhou
- Di Liu (ORCID: https://orcid.org/0000-0003-3602-770X)
- Yarong Wang
Institutions
- Guangxi University (CN)
- Dalian University of Technology (CN)
- Dalian University (CN)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-04-07
- DOI
- https://doi.org/10.1002/chem.202500536
- Citations
- 1
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.79
Funders
- National Natural Science Foundation of China
- Dalian University of Technology