The Oxidation of Cyclic Ketones by H2O2 Catalyzed by Cu(II) and Fe(III) Coordination Polymers
It has been shown that the oxidation of ketones – analogs of cyclohexanone – by hydrogen peroxide in the presence of Cu3(btc)2 (btc3- = 1,3,5-benzenetricarboxylate) occurred mainly by the radical mechanism, rather than by the Baeyer-Villiger reaction mechanism, and led to a mixture of products formed due to the ring cleavage and reduction of the hydrocarbon chain length. Unlike aliphatic ketones, α-tetralone hardly underwent conversion in the reaction with H2O2 in the presence of HKUST-1, and the oxidation of the same ketone in the presence of Fe2(OH)3(btc) led to the formation of a number of products; among them, 1,4-naphthoquinone was dominant.
Authors
- Anton Lytvynenko (ORCID: https://orcid.org/0000-0001-5528-9989)
- Konstantin S. Gavrilenko (ORCID: https://orcid.org/0000-0001-7487-6660)
- Максим А. Колосов (ORCID: https://orcid.org/0000-0002-6714-0513)
- Emir N. Abdullayev
- Elena H. Shvets (ORCID: https://orcid.org/0000-0003-4791-2114)
- Sergey V. Kolotilov (ORCID: https://orcid.org/0000-0002-4780-4378)
- Ievgenii A. Iermolenko
- A. M. Mishura
Institutions
- National Academy of Sciences of Ukraine (UA)
- Taras Shevchenko National University of Kyiv (UA)
- Institute of Organic Chemistry (UA)
- L.V. Pisarzhevskii Institute of Physical Chemistry (UA)
- Enamine (Ukraine) (UA)
- V. N. Karazin Kharkiv National University (UA)
Publication Details
- Journal
- Journal of organic and pharmaceutical chemistry
- Published
- 2025-02-19
- DOI
- https://doi.org/10.24959/ophcj.24.315358
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00