Palladium(<scp>ii</scp>)-catalyzed norbornene derivative-mediated <i>ortho</i>-C–H silylation: access to divergent silicon-containing carbazoles
A palladium( ii )-catalyzed norbornene derivative-mediated selective ortho -C–H silylation of free NH-carbazoles has been developed for the synthesis of arylsilanes. Kinetic experiments show that C–H activation is the rate-determining step.
Authors
- Man Cao
- Heyun Sheng (ORCID: https://orcid.org/0009-0005-4614-9745)
- Wenchao Gao (ORCID: https://orcid.org/0000-0002-6106-6287)
- Yongqi Yu (ORCID: https://orcid.org/0000-0001-6086-7851)
- Tao Jing (ORCID: https://orcid.org/0000-0003-4785-0988)
- Ting Li (ORCID: https://orcid.org/0000-0002-2186-6992)
- Ming Chen (ORCID: https://orcid.org/0000-0003-1533-3409)
- Wentao Li (ORCID: https://orcid.org/0000-0003-0996-8694)
- Wenguang Li (ORCID: https://orcid.org/0009-0003-4969-4621)
- Xu Zhang (ORCID: https://orcid.org/0000-0002-3588-3240)
Institutions
- Nanyang Normal University (CN)
- Hubei University of Education (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00409h
- Citations
- 4
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 3.74