Harnessing phosphorus-centered radicals for the synthesis of cyclopenta[<i>b</i>]indole and pyrrolo[1,2-<i>a</i>]indole frameworks

We report herein a highly efficient and versatile method for synthesizing phosphorus-containing cyclopenta[<i>b</i>]indole and pyrrolo[1,2-<i>a</i>]indole derivatives through a cascade radical cyclization process. The method leverages phosphorus-centered radicals to construct these polycyclic structures with high regioselectivity.

Authors

S. Chandrasekhar (ORCID: https://orcid.org/0000-0003-3695-4343)
Prathama S. Mainkar (ORCID: https://orcid.org/0000-0002-2696-3759)
Rudrakshula Madhavachary (ORCID: https://orcid.org/0000-0003-0149-5693)
Pralay Das (ORCID: https://orcid.org/0000-0003-2732-5270)
Palash Ghosh

Institutions

Indian Institute of Chemical Technology (IN)
Academy of Scientific and Innovative Research (IN)

Publication Details

Journal: Chemical Communications
Published: 2025-01-01
DOI: https://doi.org/10.1039/d5cc00906e
Citations: 4
Primary Topic: Radical Photochemical Reactions
Type: article
Field-Weighted Citation Impact: 3.74

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article

Harnessing phosphorus-centered radicals for the synthesis of cyclopenta[b]indole and pyrrolo[1,2-a]indole frameworks

S. Chandrasekhar, Prathama S. Mainkar, Rudrakshula Madhavachary, Pralay Das et al.

Jan 1, 2025

4 citations

Chemical Communications

Radical Photochemical Reactions

3.74

article

Harnessing phosphorus-centered radicals for the synthesis of cyclopenta[b]indole and pyrrolo[1,2-a]indole frameworks

S. Chandrasekhar, Prathama S. Mainkar, Rudrakshula Madhavachary, Pralay Das, Palash Ghosh

January 1, 2025article en

4 citations

Abstract

We report herein a highly efficient and versatile method for synthesizing phosphorus-containing cyclopenta[<i>b</i>]indole and pyrrolo[1,2-<i>a</i>]indole derivatives through a cascade radical cyclization process. The method leverages phosphorus-centered radicals to construct these polycyclic structures with high regioselectivity.

Chemical CommunicationsVol. 61(43)

Indian Institute of Chemical Technology (IN), Academy of Scientific and Innovative Research (IN)

Openalex Percentile: Top 8%

Radical Photochemical Reactions

3.74

DOI Source OpenAlex

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