Hydraulic and chemical cleaning efficiency for the release of microplastics retained during coagulation/flocculation-ultrafiltration

Microplastics (MPs) are ubiquitous in global drinking water sources (lakes, rivers), with reported concentrations ranging from 0.5 to >7,500 particles/L. Ultrafiltration (UF), widely applied in drinking water treatment, is anticipated to represent an effective barrier to MPs due to its pore size (0.01-0.1 µm), which can retain MPs of potential health concern. To-date limited studies have reported that MPs may contribute to UF fouling, albeit when considering concentrations up to 10 orders of magnitude higher than those typically observed in source waters. The present study evaluated the retention of MPs by UF membranes when incorporating coagulation/flocculation pre-treatment, as well as their release during hydraulic and chemical cleaning. Polyethylene (PE) fragments, representing a range of environmentally relevant sizes (1-50 µm) and concentrations (907 ± 293 particles/L), were spiked into untreated lake waters prior to coagulation/flocculation-UF. Results suggest that in the absence of coagulant (alum) addition, only 50% of MPs retained during UF permeation were subsequently released during hydraulic cleaning. The release of MPs during hydraulic cleaning decreased (<20%) at medium and high (8 mg/L, 15 mg/L) alum dosages when compared to the absence of coagulant addition. Chemical cleaning with sodium hypochlorite (500 mg/L) was only capable of releasing 20% to 60% of retained MPs. Both hydraulic and chemical cleaning were less effective for the release of MPs when compared to reversible fouling resistance, organic matter, and aluminum. As such, future research is required to determine if the accumulation of MPs leads to increased UF fouling over extended operating periods, in addition cleaning practices which specifically target MPs should be further examined. Low and medium alum dosages (2 mg/L, 8 mg/L) were observed to increase the release of retained MPs during chemical cleaning, suggesting that incorporation of coagulation pre-treatment is useful to increase the release of MPs and minimize potential long-term accumulation on membranes.