3D-printed activated carbon monoliths for efficient CO2 capture

In gas-phase adsorption processes, adsorbents are typically used as beads or pellets in a fixed bed. While these shapes permit their application in adsorption processes, they fall short of achieving optimal performance. This limitation can be greatly improved by employing structured materials, which offer reduced pressure drop and enhanced mass and energy transfer, thereby improving the overall process efficiency. Herein, resol-based activated carbons (ACs) are structured using 3D-printed sacrificial water-soluble templates to produce custom-designed monoliths for efficient carbon dioxide (CO 2 ) capture. The influence of activation conditions (time under CO 2 flow) on textural properties, CO 2 adsorption capacity, and CO 2 /nitrogen (N 2 ) selectivity are investigated. Prolonging the activation time leads to a progressive increase in surface area and micropore volume, as more carbon is removed through gasification reactions with CO 2 . The resulting enhancement in porosity improves the CO 2 adsorption capacity. However, the AC with the lowest burn-off has the highest selectivity for CO 2 over N 2 (considering a binary CO 2 /N 2 mixture with 15 mol% of CO 2 ) due to its lower ability to adsorb N 2 . Overall, this work highlights the potential of a modern 3D-printing fused deposition modeling technique to engineer structured adsorbents with applications in gas separation processes, such as CO 2 capture. • Resol-based activated carbon monoliths with interconnected channels were structured using 3D-printed templates. • The activation time under CO 2 atmosphere increases the surface area and micropore volume of the samples. • The activation time under CO 2 atmosphere increases the CO 2 adsorption capacity. • Shorter activation time increases the CO 2 selectivity for a binary mixture CO 2 /N 2 with a molar composition of 15 % CO 2 .