Electrochemical Oxidative Dibrominative Cyclization of 1,n-Enynes with Hypervalent Iodoarene Intermediates Utilizing Recyclable Bromine Ionic Liquids
An electrochemical approach with iodoarene as a mediator using recyclable ionic liquids to achieve dibromonative cyclization of 1,n-enynes has been reported. With recyclable bromine sources, <i>in situ</i> generation of iodine(III) compounds through electrochemical oxidation to achieve cyclization, a variety of heterocyclic frameworks containing both vinyl and alkyl bromide groups had been obtained in high yields with good selectivity.
Authors
- Longji Li (ORCID: https://orcid.org/0009-0009-2445-1846)
- Yang’en You (ORCID: https://orcid.org/0009-0004-2945-7079)
- Xu Wang (ORCID: https://orcid.org/0000-0002-2092-4054)
- Huaibin Jiang
Institutions
- Hefei University of Technology (CN)
- First Affiliated Hospital of Zhengzhou University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2025-04-05
- DOI
- https://doi.org/10.1021/acs.joc.5c00049
- Citations
- 2
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Henan Province
- Fundamental Research Funds for the Central Universities