Photoredox‐Catalyzed Deconstructive Thiolation and Selenylation of Pro‐Aromatic Carbocycles
Abstract Photoredox‐catalyzed aromatization‐driven deconstructive thiolation and selenylation of spiro‐dihydroquinazolinones are presented. This method, which involves C─C bond cleavage and C─S or Se bond formation, provides a facile approach to synthesizing remote and site‐specific thiolated and selenated quinazolin‐4(3 H )‐ones with good yields and functional group compatibility. A probable radical pathway is proposed for this transformation.
Authors
- Li‐Na Guo (ORCID: https://orcid.org/0000-0002-9789-6952)
- Jiayi Li (ORCID: https://orcid.org/0009-0006-6523-1952)
Institutions
- Xi’an University (CN)
- Ministry of Education (TW)
- Lanzhou University (CN)
- Xi'an Jiaotong University (CN)
Publication Details
- Journal
- ChemCatChem
- Published
- 2025-04-04
- DOI
- https://doi.org/10.1002/cctc.202500104
- Citations
- 4
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 3.74
Funders
- National Natural Science Foundation of China