Photo-induced energy transfer mediated O<sub>2</sub>-initiated deboronative generation of alkyl radicals from alkyl boronic acids and its application in radical Smiles rearrangement

A visible-light-induced, energy-transfer mechanism has been developed for the O 2 -initiated deboronative generation of alkyl radicals from alkylboronic acids, which further undergo a Smiles rearrangement reaction.

Authors

Huanhuan Song (ORCID: https://orcid.org/0009-0001-5447-8857)
Liang Xu (ORCID: https://orcid.org/0000-0002-7939-8108)
Xue Zhao (ORCID: https://orcid.org/0000-0003-1855-2543)
Shuai Liu (ORCID: https://orcid.org/0000-0003-1625-3566)
Yongsheng Tian
Jinpeng Wu (ORCID: https://orcid.org/0000-0002-1481-3454)

Institutions

Shihezi University (CN)

Publication Details

Journal: Organic Chemistry Frontiers
Published: 2025-01-01
DOI: https://doi.org/10.1039/d5qo00323g
Citations: 2
Primary Topic: Radical Photochemical Reactions
Type: article
Field-Weighted Citation Impact: 1.87

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article

Photo-induced energy transfer mediated O₂-initiated deboronative generation of alkyl radicals from alkyl boronic acids and its application in radical Smiles rearrangement

Huanhuan Song, Liang Xu, Xue Zhao, Shuai Liu et al.

Jan 1, 2025

2 citations

Organic Chemistry Frontiers

Radical Photochemical Reactions

1.87

article

Photo-induced energy transfer mediated O₂-initiated deboronative generation of alkyl radicals from alkyl boronic acids and its application in radical Smiles rearrangement

Huanhuan Song, Liang Xu, Xue Zhao, Shuai Liu, Yongsheng Tian, Jinpeng Wu

January 1, 2025article en

2 citations

Abstract

A visible-light-induced, energy-transfer mechanism has been developed for the O 2 -initiated deboronative generation of alkyl radicals from alkylboronic acids, which further undergo a Smiles rearrangement reaction.

Organic Chemistry FrontiersVol. 12(16)

Shihezi University (CN)

Openalex Percentile: Top 17%

Radical Photochemical Reactions

1.87

DOI Source OpenAlex

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Photo-induced energy transfer mediated O<sub>2</sub>-initiated deboronative generation of alkyl radicals from alkyl boronic acids and its application in radical Smiles rearrangement — Huanhuan Song, Liang Xu, et al. · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS