Highly stable bidentate thiol-protected Ag <sub>5</sub> Cu <sub>4</sub> nanoclusters: a stable catalyst for enhanced Knoevenagel condensation

The bidentate thiol-protected Ag<sub>5</sub>Cu<sub>4</sub> nanocluster exhibits exceptional stability, achieving 91% yield in the Knoevenagel condensation of benzaldehyde and malononitrile (24 h). Upon carbon black immobilization, the yield rises to 97%, demonstrating enhanced catalytic synergy and robust heterogeneous catalysis.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc00825e
Citations
1
Primary Topic
Nanocluster Synthesis and Applications
Type
article
Field-Weighted Citation Impact
0.52
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article

Highly stable bidentate thiol-protected Ag 5 Cu 4 nanoclusters: a stable catalyst for enhanced Knoevenagel condensation

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article

Highly stable bidentate thiol-protected Ag 5 Cu 4 nanoclusters: a stable catalyst for enhanced Knoevenagel condensation

Chuan Shi, Chengcheng Feng, Jiyan Dai, Chao Yang, Huayan Yang, Zhixun Zhang, Hai‐Feng Su, Xueji Zhang, Yan Nong, Xianyong Yu
article en
1 citations

Abstract

The bidentate thiol-protected Ag<sub>5</sub>Cu<sub>4</sub> nanocluster exhibits exceptional stability, achieving 91% yield in the Knoevenagel condensation of benzaldehyde and malononitrile (24 h). Upon carbon black immobilization, the yield rises to 97%, demonstrating enhanced catalytic synergy and robust heterogeneous catalysis.

Chemical CommunicationsVol. 61(38)
Hunan University of Science and Technology (CN), Shenzhen University (CN), Xiamen University (CN), University Town of Shenzhen (CN)
Openalex Percentile: Top 40%
Nanocluster Synthesis and Applications
0.52
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