Tin–Lead Perovskite Solar Cells with Enhanced Reverse Bias Stability

We address reverse bias instability in tin–lead perovskite solar cells by introducing Cr/Cu bilayer electrodes in their electron-selective contacts, which raise thermal breakdown voltage from −7.6 V to −14.5 V. Chromium prevents catastrophic device failure by mitigating hotspot shunting, being chemically stable against I2 formed during reverse bias stress.

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Publication Details

Journal
ACS Energy Letters
Published
2025-04-04
DOI
https://doi.org/10.1021/acsenergylett.5c00727
Citations
11
Primary Topic
Perovskite Materials and Applications
Type
article
Field-Weighted Citation Impact
8.03

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article

Tin–Lead Perovskite Solar Cells with Enhanced Reverse Bias Stability

Luis Lanzetta, Luis Huerta Hernandez, Derya Baran, Anirudh Sharma et al.
11 citations
ACS Energy Letters
Perovskite Materials and Applications
8.03
article

Tin–Lead Perovskite Solar Cells with Enhanced Reverse Bias Stability

Luis Lanzetta, Luis Huerta Hernandez, Derya Baran, Anirudh Sharma, Badri Vishal, Stefaan De Wolf, Xu Han
article en
11 citations

Abstract

We address reverse bias instability in tin–lead perovskite solar cells by introducing Cr/Cu bilayer electrodes in their electron-selective contacts, which raise thermal breakdown voltage from −7.6 V to −14.5 V. Chromium prevents catastrophic device failure by mitigating hotspot shunting, being chemically stable against I2 formed during reverse bias stress.

ACS Energy LettersVol. 10(5)
Kootenay Association for Science & Technology (CA), Renewable Energy Systems (United States) (US), King Abdullah University of Science and Technology (SA)
King Abdullah University of Science and Technology
Affordable and clean energy
Openalex Percentile: Top 2%
Perovskite Materials and Applications
8.03
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Tin–Lead Perovskite Solar Cells with Enhanced Reverse Bias Stability — Luis Lanzetta, Luis Huerta Hernandez, et al. · ACS Energy Letters (2025) | TGRS Research Map | TGRS